Rani has also performed a Lavani number in the movie, which releases October 12.
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Rani will be seen doing belly dancing in the hot song "Aga bai".
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Prithviraj has acted in Malayalam, Tamil and Telugu films and his notable performances include Vaasthavam, Indian Rupee, Classmates, Mani Ratnam's Tamil version of Raavanan, Urumi and others.
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Entertaining masses is Rani's aim. "I think the success of a film is very important to an actor. It depends on how many people go to watch your movies; the more the merrier. Nobody wants to do a film for five people. You work so hard that millions of people watch the movie; this is directly related to box office success."
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Prithviraj can't stop heaping praises for Rani. "She is fantastic. She is so inclusive as an actor, she used to go out of her way to make sure not just me but every actor on the sets is comfortable in their own space. She used to call the entire team to her house, discuss scenes and how we will approach towards scenes," he said.
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Directed by debutant Sachin Kundalkar, Aiyyaa is story about a woman who finds a man desirable because he smells good.
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She was last seen in political crime thriller No One Killed Jessica that released early last year and earned critical acclaim.
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Rani has delivered several hit films like Kuch Kuch Hota Hai, Black, Hum Tum and Veer Zaara among others.
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Rani plays the role of a Marathi girl who falls in love with a Malayalam boy, played by the South actor.
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Check out the sizzling chemistry of Rani Mukherji and her co-star Prithviraj in the upcoming film Aiyyaa.